Mestrado em Engenharia Ambiental
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- ItemAvaliação da disposição a pagar pelo manejo de resíduos gerados em condomínios residenciais e efeito na sustentabilidade financeira da gestão integrada de resíduos sólidos urbanos(Universidade Federal do Espírito Santo, 2024-08-12) Mascarenhas, Vitor Souza Pinto; Yamane, Luciana Harue ; https://orcid.org/; http://lattes.cnpq.br/; Co-orientador2; https://orcid.org/; http://lattes.cnpq.br/; Co-orientador3; https://orcid.org/; http://lattes.cnpq.br/; Co-orientador4; ID do co-orientador4; Lattes do co-orientador4; Siman, Renato Ribeiro ; https://orcid.org/; http://lattes.cnpq.br/; Orientador2; https://orcid.org/; http://lattes.cnpq.br/; https://orcid.org/; http://lattes.cnpq.br/; Chaves, Gisele de Lorena Diniz; https://orcid.org/; http://lattes.cnpq.br/; Günther, Wanda Maria Risso; https://orcid.org/; http://lattes.cnpq.br/; 3º membro da banca; https://orcid.org/; http://lattes.cnpq.br/; 4º membro da banca; http://lattes.cnpq.br/; 5º membro da banca; https://orcid.org/; http://lattes.cnpq.br/; 6º membro da banca; https://orcid.org/; http://lattes.cnpq.br/; 7º membro da banca; https://orcid.org/; http://lattes.cnpq.br/This study evaluated Brazilian residential condominiums in the Solid Waste Management (SWM), focusing on the economic-financial sustainability in the provision of management services. For this purpose, a systematic review was carried out identifying the normative acts that deal with residential condominiums and charging for management services, and the aspects that influence the Willingness To Pay (WTP) for these services. In addition, a case study was conducted in the municipality of Vitória/ES, identifying through a questionnaire and the Contingent Valuation Method, the WTP for Waste Management in condominiums, and estimating the financial impact with the application of a transfer policy of responsibility. From the systematic review it was identified that there is no specific Brazilian legislation for charging for management services in residential condominiums. It was also identified that the influential variables in WTP are divided into four groups: (1) socioeconomic aspects, (2) informational level, (3) situation of management services, and (4) political and regulatory aspects, being the last still little studied despite representing a strong influence on WTP. The case study revealed that 58% of the interviewees living in condominiums are willing to pay an average of R$ 29.41 per month per household for management services, and this amount could be increased by 15% by disclosing information about the WTP. Finally, it was identified that the costs of waste management in residential condominiums correspond to around 23% of the entire SWM cost in Vitória/ES, and that the application of a responsibility transfer policy can relieve 19% of the costs. This work contributes to the development of policies for charging for waste management services in residential condominiums, describing the WTP, and the importance of disclosing information for greater acceptance of the policy. Due to the low adherence of interviewees, future studies are recommended to construct statistically representative scenarios and econometric models, which allow the calculation of the WTP and the assessment of the financial impact
- ItemAvaliação da remoção de 2,4-d e atrazina por carvão ativado : um estudo da competição em adsorção(Universidade Federal do Espírito Santo, 2024-09-24) Rafalscky, Lays; Britto, Gilberto Maia; https://orcid.org/; http://lattes.cnpq.br/; Co-orientador2; https://orcid.org/; http://lattes.cnpq.br/; Co-orientador3; https://orcid.org/; http://lattes.cnpq.br/; Co-orientador4; ID do co-orientador4; Lattes do co-orientador4; Coelho, Edumar Ramos Cabral; https://orcid.org/; http://lattes.cnpq.br/; Orientador2; https://orcid.org/; http://lattes.cnpq.br/; https://orcid.org/; http://lattes.cnpq.br/; Gonçalves, Ricardo Franci; https://orcid.org/; http://lattes.cnpq.br/; Capelo Neto, José; https://orcid.org/; http://lattes.cnpq.br/; 3º membro da banca; https://orcid.org/; http://lattes.cnpq.br/; 4º membro da banca; http://lattes.cnpq.br/; 5º membro da banca; https://orcid.org/; http://lattes.cnpq.br/; 6º membro da banca; https://orcid.org/; http://lattes.cnpq.br/; 7º membro da banca; https://orcid.org/; http://lattes.cnpq.br/The presence of pesticides in drinking water is concerning due to the toxicity and bioaccumulation potential of these compounds. In this context, adsorption by activated carbon has gained attention as an alternative for removing microcontaminants in water treatment. Several variables can influence adsorption, one of the most notable being the competition among multiple contaminants for the adsorption sites on the activated carbon. This work conducted a systematic review guided by the PRISMA guideline to establish the state of the art on competitive adsorption. The review data were obtained using the keywords “Competitive adsorption,” “Powder Carbon” “Activated Carbon,” and “Water Treatment,” covering the years 2000 to 2023. The selected articles were categorized into: competition between metals, competition between metals and organic compounds, and competition between organic compounds. The review results contributed to understanding the existing research gaps in the field. In the laboratory tests, the activated carbon was characterized by several techniques to identify functional groups, porosity, moisture content, and ash content, among other parameters. Then, the isolated and competitive removal of two highly commercialized herbicides in Brazil, atrazine and 2,4-D, was tested in the state of Espírito Santo, with adsorption evaluated in terms of kinetics and isotherms. The Freundlich model showed the best fit for both pesticides in isolated systems. The adsorption of 2,4-D was significantly affected by the presence of atrazine due to its hydrophilic nature in the study's pH range (6-7). A computational study was conducted to suggest potential mechanisms, and the results indicated a predominance of π-π interactions, which is consistent with findings in the literature. The results suggest that the commercial carbon from Bahia Carbon is a strong candidate for removing 2,4-D and atrazine in isolated systems, but the presence of atrazine may significantly affect the removal of 2,4-D