Novel neutral iron(II) isocyanide maleonitrile dithiolate [Fe(S2C2(CN)2)(t-BuNC) 4] compound

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dc.date.accessioned2011-02-07T19:49:55Z
dc.date.available2011-02-07T19:49:55Z
dc.identifier.citationMORIGAKI, Milton K. et al. Novel neutral iron(II) isocyanide maleonitrile dithiolate [Fe(S2C2(CN)2)(t-BuNC) 4] compound. Quím. Nova, São Paulo, v. 27, n. 1, p. 76-78, jan./fev. 2004. Disponível em: <http://www.scielo.br/pdf/qn/v27n1/18814.pdf>. Acesso em: 28 jan. 2011.por
dc.identifier.doi10.1590/S0100-40422004000100016
dc.identifier.issn0100-4042
dc.identifier.urihttp://repositorio.ufes.br/handle/10/539
dc.rightsopen accessen
dc.titleNovel neutral iron(II) isocyanide maleonitrile dithiolate [Fe(S2C2(CN)2)(t-BuNC) 4] compoundpor
dc.typearticleen
dcterms.abstractFeBr2 reacts with the S2C2(CN)22- ion (1:1 ratio) in the presence of an excess of t-BuNC in THF to give the mixed ligand [Fe(S2C2(CN)2)(t-BuNC) 4] compound. This neutral product with a formal oxidation state of two for the iron atom was characterized by conductivity measurements, and, i.r., Mössbauer, 13C and 1H n.m.r. spectroscopy. There is a Fe-C p back-donation strengthened towards isocyanide ligands, according to the data of 13C, 1H n.m.r. and Mössbauer spectroscopy.eng
dcterms.creatorMorigaki, Milton Koiti
dcterms.creatorSilva, Elias Meira da
dcterms.creatorMelo, Carlos Vital Paixão de
dcterms.creatorLarica, Carlos
dcterms.creatorBiondo Filho, Armando
dcterms.creatorFreitas, Jair Carlos Checon de
dcterms.creatorDias, Gilson Herbert Magalhaes
dcterms.creatorRibeiro, Holgadinei Rodrigues
dcterms.issued2004-01
dcterms.languageengen
dcterms.subjectFerropor
dcterms.subjectMössbauer, Espectroscopia depor
dcterms.subjectIsocianetospor
dcterms.subjectIroneng
dcterms.subjectIsocyanideeng
dcterms.subjectDithiolateeng
dcterms.subjectSpectroscopy, Mossbauereng
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